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When composing a new email message with WebAsyst Mail you can select a sender in the "From" list. If the desired sender is missing in that list, add it there by creating a new mail box with the email address that should be used as the sender.
Tip: If you are not planning to receive mail at the new mailbox and are creating it only to be able to select a certain sender for outgoing emails, you may enter arbitrary (even incorrect) data in its settings. Remember that in this case you will not be able to receive replies to such messages using WebAsyst Mail!